Q235B带钢边裂分析

通过对带钢Q235B边裂缺陷进行检验和分析,认为造成此次带钢边裂的主要原因是铸坯边部细小裂纹、深振痕、皮下气泡、针孔以及轧钢划伤引起的,通过采取措施减少铸坯边部缺陷和划伤,可以减少边裂缺陷。     

基于多因素耦合分析的冲击地压卸压技术研究

为有效预防ZF2803工作面的冲击地压,本文采用多因素耦合分析法研究了初次来压、见方、煤柱、断层、邻近空区支承压力、煤层厚度变化及巷道底煤等7个因素的单独影响区域及叠加效果,确定了7个危险区:中等冲击危险区4个、强冲击危险区3个,给出了相应的煤层及底板大钻孔预卸压措施,工业性应用取得了良好的防治效果。     

Photopolymerization synthesis of polyacrylic acid dispersant with methoxysilicon end groups and its application in a nano‐SiO2 aqueous system

In order to improve the dispersity and stability of the nano‐SiO₂ aqueous system with high solid content, a kind of polyacrylic acid dispersant with methoxysilicon end groups (KH590‐PAA) was synthesized by photopolymerization of acrylic acid (AA) initiated with (3‐mercaptopropyl)trimethoxysilane (KH590). After adding KH590‐PAA into the nano‐SiO₂ aqueous dispersion system (20 wt% solid content), the viscosity and the curing time of the system were measured with a rotational viscometer and the inverted bottle method. Moreover, the dispersion mechanism of KH590‐PAA for the nano‐SiO₂ aqueous system was researched by measuring the adsorption capacity, the particle size and the zeta potential of the nanoparticles with a conductivity meter, dynamic light scattering, SEM and TEM, respectively. The results showed that the methoxysilicon groups in KH590‐PAA could react with hydroxyl groups on the surface of nano‐SiO₂ in the process of stirring, which enhanced the adsorption capacity of the dispersant and then increased the surface charge of the particles. Therefore, electrostatic repulsion and steric hindrance effects between the SiO₂ nanoparticles could be further enhanced by adding the KH590‐PAA dispersant, and then the nano‐SiO₂ aqueous system exhibited better dispersity and stability. Besides, the dispersion properties of SiO₂ nanoparticles in water were closely related to the addition amount and the molecular weight of the KH590‐PAA dispersant. © 2018 Society of Chemical Industry     

Interface control for resolved CFD-DEM with capillary interactions

In this work, a resolved CFD–DEM coupling model for the simulation of gas-liquid-solid flows is developed: the interface capturing method based on the colour function is employed for fluids (i.e. a gas and liquid) whilst Discrete Element Method (DEM) is used for particles. The Volume Penalisation (VP) method is adopted to consider the hydrodynamic interactions between fluids and particles along with the Immersed Free Surface (IFS) method, which artificially extends the gas-liquid interface into the interior of the particle to account for the wettability. The unique point of the proposed model is that the thickness of the gas-liquid interface can be controlled by using both interface compression and diffuse interface techniques simultaneously. From the simulation results, it is presented that the accurate evaluation of the surface tension force as well as the capillary force can be achieved by appropriately controlling the interface thickness. Moreover, the major two methods in the literature to calculate the capillary force are compared in this work. The validity of the proposed model is presented for both static and dynamic cases. The behaviour of two colliding particles with a dynamic liquid bridge is then simulated to demonstrate the applicability of the proposed model to a complex three-phase system.     

基于HHT-RDT算法的高拱坝泄流结构工作模态识别方法

根据高拱坝泄流结构自身的工作特点,为准确辨识环境激励下的结构模态参数特征,提出了一种基于改进的HHT-RDT算法的高拱坝泄流结构工作模态识别方法。以某高拱坝原型振动响应测试资料为基础,利用改进的小波阈值-EMD算法对原始信号进行降噪预处理,滤除干扰噪声的同时保留有效特征信息;采用HHT-RDT算法识别高拱坝泄流结构的工作模态参数,运用带通滤波对振动响应信号的EMD过程进行控制得到结构的各阶模态分量,利用RDT法提取各阶模态分量的自由衰减信息,识别出高拱坝泄流结构系统的固有频率及阻尼比。工程实例表明,该方法避免了复杂系统定阶过程,有效提高结构振动响应工作模态识别精度,为辨识高拱坝泄流结构的工作模态参数提供捷径。     

转子/密封系统失稳振动抑制的动力吸振方法研究

针对密封中流体引起转子/密封系统振动失稳的问题。提出采用动力吸振器(DVA)实现转子/密封系统失稳振动抑制。建立转子/密封-DVA系统非线性微分方程,采用数值方法求解并获得附加DVA前后转子/密封系统的非线性特性;根据Hurwitz判据获得系统的临界稳定条件;通过遗传算法优化DVA参数,获得附加优化DVA前后转子/密封系统稳定性。结果表明:附加DVA能够改变转子/密封系统失稳振动频率和失稳阈值;在一定的转速范围内失稳振动被完全抑制;在不完全抑制的转速范围内,附加DVA能降低失稳振动的振幅。     

Environmental Control of Triplet Emission in Donor–Bridge–Acceptor Organometallics

Carbene‐metal‐amides (CMAs) are a promising family of donor–bridge–acceptor molecular charge‐transfer (CT) emitters for organic light‐emitting diodes. A universal approach is demonstrated to tune the energy of their CT emission. A blueshift of up to 210 meV is achievable in solid state via dilution in a polar host matrix. The origin of this shift has two components: constraint of thermally‐activated triplet diffusion, and electrostatic interactions between guest and polar host. This allows the emission of mid‐green CMA archetypes to be tuned to sky blue without chemical modifications. Monte‐Carlo simulations based on a Marcus‐type transfer integral successfully reproduce the concentration‐ and temperature‐dependent triplet diffusion process, revealing a substantial shift in the ensemble density of states in polar hosts. In gold‐bridged CMAs, this shift does not lead to a significant change in luminescence lifetime, thermal activation energy, reorganization energy, or intersystem crossing rate. These discoveries offer new insight into coupling between the singlet and triplet manifolds in CMA materials, revealing a dominant interaction between states of CT character. The same approach is employed using materials which have been chemically modified to alter the energy of their CT state directly, shifting the emission of sky‐blue chromophores into the practical blue range.     

基于小波时频图和卷积神经网络的断路器故障诊断分析

高压断路器操动机构振动信号为非平稳性信号,蕴含着丰富的操动机构工作状态的信息,对操动机构工作状态的检验辨识具有重大意义。提出一种基于小波时频图和卷积神经网络的断路器故障诊断方法。对操动机构振动信号进行连续小波变换生成时频图(CWT),并对时频图进行统一压缩预处理;将预处理后的时频图作为特征图输入卷积神经网络AlexNet模型;通过对网络参数的调整,逐步改进网络模型,有监督地实现对操动机构故障状态的辨识诊断。结果表明,该方法能够有效地运用于断路器操动机构故障辨识诊断,与小波频带能量-RBF、小波频带能量-SVM的故障识别相比,故障识别准确率最高。